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⚗️
CHAPTER 3

Chemical Reactions and Equations

Science Part 1 • Class 10th

In this chapter

⭐ Study Focus

Learn how to identify, write, balance and classify chemical reactions.

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1 • CHEMICAL CHANGE

Physical and Chemical Change

During a physical change, generally only the state of matter changes and the composition remains the same.

A physical change is often reversible.

During a chemical change, the composition of matter changes and the change is generally permanent.

Examples

Physical changesChemical changes
Ice → waterCooking of food
Water → iceMilk → curd
Evaporation of waterDigestion of food
Breaking glassRipening of fruit
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2 • REACTION

Chemical Reaction

Definition

A chemical reaction is a process in which some substances undergo bond breaking and are transformed into new substances by formation of new bonds.

Reactants

The substances taking part in a chemical reaction are called as reactants.

Products

The substances formed as a result of a chemical reaction by formation of new bonds are called as products.

Carbon + Oxygen → Carbon dioxide
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3 • EQUATION

Chemical Equation

A chemical reaction can first be represented using words. This is a word equation.

Copper sulphate + Zinc → Zinc sulphate + Copper

It can then be written in condensed form using chemical formulae.

Definition

The representation of a chemical reaction in a condensed form using chemical formulae is called as a chemical equation.

CuSO₄ + Zn → ZnSO₄ + Cu
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4 • WRITING

Rules for Writing a Chemical Equation

  1. Reactants are written on the left-hand side.
  2. Products are written on the right-hand side.
  3. An arrow is placed between them to show direction.
  4. Two or more reactants/products are joined by a + sign.
  5. Physical states can be shown as (g), (l), (s), and (aq).
  6. Conditions such as heat, temperature, pressure or catalyst can be written above/below the arrow.
CuSO₄(aq) + Zn(s) → ZnSO₄(aq) + Cu(s)
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5 • CONDITIONS

Conditions of a Reaction

Some reactions require heat, a specific temperature, pressure or catalyst.

CaCO₃(s) —Δ→ CaO(s) + CO₂(g)

Here Δ indicates heating.

Vegetable oil + H₂ —Ni, 60°C→ Vanaspathi ghee

Here nickel acts as a catalyst.

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6 • BALANCING

Balanced Chemical Equation

Definition

A chemical equation in which the number of atoms of each element is the same on both sides of the equation is called as a balanced equation.

Unbalanced equation

An equation in which the number of atoms of each element is not the same on both sides is called as an unbalanced equation.

⭐ Law

Total mass of each element remains the same on both sides. This follows the law of conservation of mass.

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7 • BALANCING

Balancing by Trial and Error

Example:

NaOH + H₂SO₄ → Na₂SO₄ + H₂O

Step 1

Na is not balanced. Put coefficient 2 before NaOH.

2NaOH + H₂SO₄ → Na₂SO₄ + H₂O

Step 2

Hydrogen is not balanced. Put coefficient 2 before water.

2NaOH + H₂SO₄ → Na₂SO₄ + 2H₂O
⭐ Important Rule

While balancing an equation, do not change the formula of a compound. Change only appropriate coefficients.

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8 • TYPES

Types of Chemical Reactions

Chemical reactions are classified into four types according to the nature and number of reactants and products.

⭐ Four Types

1. Combination
2. Decomposition
3. Displacement
4. Double displacement

A + B → AB
AB → A + B
A + BC → AC + B
AB + CD → AD + CB
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9 • COMBINATION

Combination Reaction

Definition

The reaction in which two or more reactants combine to form a single product is called as a combination reaction.

2Mg + O₂ → 2MgO
CaO + H₂O → Ca(OH)₂ + Heat
⭐ Pattern

Many reactants → One product

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10 • DECOMPOSITION

Decomposition Reaction

Definition

The chemical reaction in which two or more products are formed from a single reactant is called as a decomposition reaction.

C₁₂H₂₂O₁₁ → 12C + 11H₂O
CaCO₃ —Δ→ CaO + CO₂

Calcium carbonate decomposes on heating. Carbon dioxide turns freshly prepared lime water milky.

⭐ Pattern

One reactant → Two or more products

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11 • ELECTROLYSIS

Electrolysis as Decomposition

Water can be decomposed by passing electric current through acidulated water.

2H₂O —Electrical Energy→ 2H₂ + O₂

This decomposition by electric current is called as electrolysis.

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12 • DISPLACEMENT

Displacement Reaction

Definition

The reaction in which the place of the ion of a less reactive element in a compound is taken by another more reactive element by formation of its own ions is called as a displacement reaction.

CuSO₄ + Zn → ZnSO₄ + Cu
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13 • DOUBLE

Double Displacement Reaction

Definition

The reaction in which the ions in the reactants are exchanged to form a precipitate is called as a double displacement reaction.

AgNO₃(aq) + NaCl(aq) → AgCl↓ + NaNO₃(aq)

Silver chloride is formed as a white precipitate. Ions in the reactants exchange with each other.

⭐ Pattern

Ion exchange → precipitate → double displacement reaction

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14 • HEAT

Endothermic and Exothermic

Endothermic process

The process in which heat is absorbed from the outside is called as an endothermic process.

Exothermic process

The process in which heat is given out is called as an exothermic process.

EndothermicExothermic
Heat absorbedHeat released
Example: CaCO₃ decompositionExample: CaO + H₂O
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15 • ENDOTHERMIC

Endothermic Reaction

Definition

A chemical reaction in which heat is absorbed from the surroundings or supplied continuously from outside is called as an endothermic reaction.

CaCO₃(s) + Heat → CaO(s) + CO₂(g)

Examples of endothermic processes include melting of ice and dissolution of potassium nitrate in water.

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16 • EXOTHERMIC

Exothermic Reaction

Definition

A chemical reaction in which heat is given away when reactants are transformed into products is called as an exothermic reaction.

CaO(s) + H₂O(l) → Ca(OH)₂(aq) + Heat

Examples of exothermic processes include formation of ice from water and dissolution of sodium hydroxide in water.

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17 • RATE

Rate of Chemical Reaction

Some chemical reactions occur rapidly while some occur slowly.

Fast reactions

Burning of cooking gas; effervescence on adding baking soda to dilute acid; formation of a white precipitate.

Slow reactions

Rusting of iron; erosion of rocks; formation of alcohol under proper conditions.

Therefore, the rate of different chemical reactions is different.

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18 • FACTORS

Factors Affecting Rate of Reaction

  1. Nature of reactants – different substances have different reactivities.
  2. Size of particles – smaller particles have larger exposed surface.
  3. Concentration – higher concentration generally increases rate.
  4. Temperature – increasing temperature increases rate.
  5. Catalyst – can increase rate without being chemically changed.
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19 • FACTORS

Particle Size and Concentration

Size of particles

Powder reacts faster than larger pieces because smaller particles expose a larger surface.

Trend

Particle size ↓ → Rate of reaction ↑

Concentration

Concentrated HCl reacts faster with calcium carbonate than dilute HCl.

Trend

Concentration ↑ → Rate of reaction ↑

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20 • FACTORS

Temperature and Catalyst

Temperature

Increasing temperature increases the rate of a chemical reaction.

Trend

Temperature ↑ → Rate of reaction ↑

Definition

The substance in whose presence the rate of a chemical reaction increases, without causing any chemical change to it, is called as a catalyst.

2KClO₃ —MnO₂→ 2KCl + 3O₂

Manganese dioxide increases the rate of decomposition of potassium chlorate and itself does not undergo chemical change.

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21 • OXIDATION

Oxidation Reaction

Definition

The chemical reaction in which a reactant combines with oxygen or loses hydrogen to form the product is called as an oxidation reaction.

2Mg + O₂ → 2MgO
C + O₂ → CO₂
⭐ Electron concept

Oxidation means losing one or more electrons.

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22 • OXIDANTS

Oxidants / Oxidizing Agents

Definition

The substances which bring about an oxidation reaction by making oxygen available are called as oxidants or oxidizing agents.

Common oxidants include:

Nascent oxygen

Nascent oxygen is represented by [O] and is the reactive form of oxygen before formation of O₂.

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23 • REDUCTION

Reduction Reaction

Definition

The chemical reaction in which reactants gain hydrogen is called as a reduction reaction.

Another form

The reaction in which a reactant loses oxygen to form the product is also called as a reduction reaction.

CuO + H₂ → Cu + H₂O
⭐ Electron concept

Reduction means gaining one or more electrons.

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24 • REDOX

Redox Reaction

Definition

A reaction in which oxidation and reduction take place simultaneously is called as a redox reaction.

CuO + H₂ → Cu + H₂O
SubstanceChange
CuOReduction
H₂Oxidation
⭐ Memory

Oxidation + Reduction = Redox reaction

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25 • CHARGE

Oxidation and Reduction – Charge Concept

OxidationReduction
Loss of electronsGain of electrons
Positive charge increasesPositive charge decreases
Negative charge decreasesNegative charge increases
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26 • CORROSION

Corrosion

Definition

The damage of metals due to oxidation caused by various components of the atmosphere is called as corrosion.

Corrosion is an oxidation process. Rusting of iron is an important example.

⭐ Important

Both water and air are necessary for rusting. Rusting occurs rapidly in the presence of salt.

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27 • RUSTING

Rusting of Iron

Rust is a reddish coloured solid layer formed on iron.

Rust = Fe₂O₃ · xH₂O

Rust is formed through an electrochemical reaction. Different regions of the iron surface act as anode and cathode.

At anode

Fe → Fe²⁺ + 2e⁻

At cathode

O₂ + 4H⁺ + 4e⁻ → 2H₂O
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28 • RANCIDITY

Rancidity

Definition

The foul odour and change in taste produced when oil or ghee undergoes air oxidation is called as rancidity.

Prevention

⭐ Board Focus

Revise balancing, four reaction types, endothermic/exothermic reactions, rate factors, oxidation/reduction, corrosion and rancidity.

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FINAL REVISION

Chapter 3 – Quick Revision

Reaction types

Combination → Many reactants, one product
Decomposition → One reactant, many products
Displacement → More reactive element displaces less reactive element
Double displacement → Exchange of ions

Rate factors

Nature • Particle size • Concentration • Temperature • Catalyst

Redox

Oxidation + Reduction = Redox

Corrosion

Metal damage due to atmospheric oxidation.

Rancidity

Foul odour and change in taste due to air oxidation of oil/ghee.

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